I've been pretty transparent about the fact that the best PC upgrade is one that costs exactly zero dollars. But aside from that? The next-best thing is using stuff you might already have lying around to give your PC a bit of a boost. If you keep most of your old hardware, chances are you'll have one (or some) of these in a drawer somewhere, and they could come in handy when you least expect it.
How-To Geek
8 free PC upgrades hiding in your junk drawer
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